Title of article
Highly stable methylaluminum dimer complex with chiral tridentate ligand
Author/Authors
Min Jeong Go، نويسنده , , So Han Kim، نويسنده , , Yi Young Kang، نويسنده , , Hyoung-Ryun Park، نويسنده , , Youngjo Kim، نويسنده , , Junseong Lee، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
4
From page
139
To page
142
Abstract
The dimeric aluminum complex containing fully deprotonated 4-{[(1S,2R)-2-hydroxyindan-1-yl]amino}-pent-3-en-2-one was synthesized and characterized. X-ray analysis revealed that the two five-coordinate aluminum centers possess ideal tetragonal pyramid geometry and two methyl groups are located in cis position. It is found to be stable in the presence of isopropanol at room temperature. The compound was used as a catalyst for the ring opening polymerization of lactide accompanying lactide epimerization.
Keywords
chiral ligand , Dimeric aluminum complex , Schiff base ligand , Ring opening polymerization , Epimerization , Polylactide
Journal title
Inorganic Chemistry Communications
Serial Year
2014
Journal title
Inorganic Chemistry Communications
Record number
1315396
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