Title of article
Cationic olefin Pd(II) complexes bearing α-iminoketone N,O-ligands: unprecedented isomerisation of the methoxycyclooctenyl ligand
Author/Authors
Alceo Macchioni، نويسنده , , Cristiano Zuccaccia، نويسنده , , Barbara Binotti، نويسنده , , Carla Carfagna، نويسنده , , Elisabetta Foresti، نويسنده , , Piera Sabatino، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
4
From page
319
To page
322
Abstract
The reaction of [Pd(η1,η2-C8H12OMe)Cl]2 with α-iminoketone ligands affords cationic η1,η2-5-methoxycyclooctenyl Pd(II) complexes, the intramolecular and interionic structures of which were investigated in both solution and solid state; such complexes undergo unprecedented isomerisation to η1,η2-1-methoxycyclooctenyl complexes assisted by weak nucleophiles such as olefins or alkynes.
Keywords
Palladium compounds , O-ligands , N , X-ray structure , 1D- and 2D-NMR spectroscopy
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315559
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