Title of article
Heterobimetallic lithium organoaluminum and organogallium complexes: potential single precursors for MOCVD of LiMO2 thin films
Author/Authors
Eunhee Jung، نويسنده , , Seung H Yoo، نويسنده , , Taek-Mo Chung، نويسنده , , Chang G Kim، نويسنده , , Yunsoo Kim ، نويسنده , , Duk-Young Jung، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
3
From page
439
To page
441
Abstract
The reaction of Me2MCl with two equivalents of Li(OCH2CH2OMe) resulted in the formation of dimeric bimetallic complexes, [Li(OCH2CH2OMe)2MMe2]2 {M=Al (1), Ga (2)}. The crystal structures of 1 and 2 are dimeric and contain eight-membered rings that are similar to a beach chair consisting of a plane of four oxygen and two lithium atoms with each aluminum or gallium metal atom above and below this plane. Thermal analysis of 2 indicates that the dimeric complexes are volatile enough to be suitable as potential single precursors for metal organic chemical vapor deposition (MOCVD) of LiMO2 films.
Keywords
Single precursor , MOCVD , LiGaO2 , LiAlO2
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315594
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