Title of article :
Chlorobis(pentafluorophenyl)alane: synthesis, crystal structure, and polymerization catalysis
Author/Authors :
Debashis Chakraborty، نويسنده , , Eugene Y.-X. Chen، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
Reaction of Al(C6F5)3 with 0.34 equiv CH2Cl2 cleanly produces chlorobis(pentafluorophenyl)alane (C6F5)2AlCl, the dimeric structure in the solid-state of which has been confirmed by X-ray diffraction studies. This chloroalane exhibits remarkable activity in polymerizations of styrene, ε-caprolactone, and cyclohexene oxide.
Keywords :
Organoalane , Alane , Catalyst , Polymerization catalysis
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
