Title of article :
Synthesis and electro-catalytic properties of a dinuclear triazenido-palladium complex
Author/Authors :
Jing Chu، نويسنده , , Qi-ying Lv، نويسنده , , Jie-ping Cao، نويسنده , , Xiaohua Xie، نويسنده , , Shuzhong Zhan، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
The reaction of 1,3-bis[(4-chloro)benzene]triazene (HL) and [Pd(CH3CN)4]Cl2 gave a dinuclear triazenido complex Pd2L4 1, which has been characterized by 1H NMR spectrum and X-ray crystallography. Electrochemical studies showed that complex 1 is capable of generating hydrogen from acetic acid in DMF with icat/ip ~ 7.5.
Keywords :
Triazenido-palladium complex , crystal structure , Molecular electro-catalyst , Hydrogen evolution
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
