Title of article
Synthesis of ruthenium (II) complexes containing a dihydroperimidine-derived phosphine ligand and their application in transfer hydrogenation of ketones
Author/Authors
Qi Fu، نويسنده , , Lei Zhang، نويسنده , , Tao Yi، نويسنده , , Mingjun Zou، نويسنده , , Xiaoyan Wang، نويسنده , , Haiyan Fu، نويسنده , , Ruixiang Li، نويسنده , , Hua Chen، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
28
To page
32
Abstract
The new ruthenium (II) phosphine complexes (η6-C6H6)RuCl2[μ- (PPh2CH2N)2CH2(C10H6)]RuCl2(η6-C6H6) (1) and RuCl2(PPh3)[(PPh2CH2N)2CH2(C10H6)] (2) were synthesized and characterized by 1H NMR, 31P {1H} NMR and elemental analysis. Moreover, the structure of ruthenium (II) phosphine complex 1 was confirmed by X-ray crystallography. With complex 1 as the catalyst, the transfer hydrogenation of ketones reacted well, affording the corresponding alcohols in good yields under mild conditions.
Keywords
Phosphine , Transfer hydrogenation , Ketone , Ruthenium
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1315798
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