Title of article
Optically active complexes (μ-H)Os3(μ-OCNH-(R)-CHMePh)(CO)10: the absolute configuration of the (+)-rotating stereoisomer
Author/Authors
Victoria A. Ershova، نويسنده , , Alexander V. Virovets، نويسنده , , Vladimir M. Pogrebnyak، نويسنده , , Anatoly V. Golovin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
3
From page
963
To page
965
Abstract
Room-temperature interaction between Os3(CO)11NCMe and (R)-(+)-1-phenylethylamine at ambient temperature in THF gives two known diastereomeric clusters (μ-H)Os3(μ-OCNH-(R)-CHMePh)(CO)10 in an approximate ratio 1:2. 1H-NMR, IR and [α]D characteristics are described for them. The (+)-diastereomer characterized by absolute-configugational data obtained from the X-ray analysis of its single crystal.
Keywords
Triosmium chiral clusters , Absolute configuration , X-ray analysis
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315864
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