Title of article
Catalytic oxidation of THF with homo and hetero metallic Mo/Ru complexes and molecular oxygen
Author/Authors
Thomas Straub، نويسنده , , Ari M.P. Koskinen، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
4
From page
1052
To page
1055
Abstract
The novel complex Ind(CO)3Mo–Ru(CO)2Cp (1) (Ind=η5-indenyl,Cp=η5-cyclopentadienyl), as well as other hetero and homo metallic complexes of molybdenum and ruthenium are catalyst precursors in the aerobic oxidation of THF under ambient conditions. Selectivities towards γ-butyrolactone of up to 70% are obtained. For the first time in this transformation, propylformate is isolated besides the lactone.
Keywords
Molybdenum , Hetero bimetallic , Catalytic aerobic oxidation , cyclic ether , Ruthenium complex
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315886
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