Title of article
μ3-SH dicapped triangular copper(I) complex of bis(diphenylphosphino)amine
Author/Authors
Lei Han، نويسنده , , Lin-Xi Shi، نويسنده , , Li-Yi Zhang، نويسنده , , Zhong-Ning Chen، نويسنده , , Mao-Chun Hong، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
3
From page
281
To page
283
Abstract
The reaction between [Cu2(Ph2PNHPPh2)2(MeCN)2](BF4)2 and sodium salt of mercaptoacetic acid (HSCH2COONa) at room temperature for 12 h produced a doubly μ3-SH-bridged tricopper complex [Cu3(μ-Ph2PNHPPh2)3(μ3-SH)2](BF4)·2MeOH·Et2O which affords a trigonal bipyramidal core of Cu3(μ3-SH)2 with copper ⋯ copper separations around 3.0 Å. The complex is photoluminescent and it displays an emissive maximum at 523 nm in the solid state at 293 K.
Keywords
Sulfhydryl , Trinuclear , Bis(diphenylphosphino)amine , Copper(I)
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1315963
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