Title of article
(R=alkyl or aryl) complexes as catalysts for ethylene polymerization
Author/Authors
M.F.N.N Carvalho، نويسنده , , K Mach، نويسنده , , A.R Dias، نويسنده , , J.F Mano، نويسنده , , M.M. Marques، نويسنده , , A.M Soares، نويسنده , , A.J.L. Pombeiro، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
331
To page
334
Abstract
(R=alkyl or aryl) complexes in combination with methylaluminoxane were found to be highly efficient catalysts towards ethylene polymerization. The species with aromatic R groups display higher activity than those with aliphatic ones. This tendency could not be correlated with the electronic properties of the complexes that were evaluated by cyclic voltammetry. The polyethylenes obtained in the catalytic processes were characterized by 1H NMR and DSC.
Keywords
Catalysis , polymerization , Ethylene , titanium complexes , Electrochemistry
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1315975
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