Title of article :
Inorganic–organic hybrid material containing β-cage: {[H2(en)]Co2(ox)(V4O12)}n
Author/Authors :
Cheng-Ling Pan، نويسنده , , Ji-Qing Xu*، نويسنده , , Kaixue Wang، نويسنده , , Xiao-Bing Cui، نويسنده , , Ling Ye، نويسنده , , Zheng-Liang Lü، نويسنده , , De-Qing Chu، نويسنده , , Tie-Gang Wang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
By using an organic ligand, a new inorganic–organic hybrid compound of cobalt oxalate-vanadate, {[H2(en)]Co2(ox)(V4O12)}n 1, where en = ethylenediamine, ox = oxalic acid, has been synthesized hydrothermally from V2O5,CoCl2·6H2O,H2C2O4·2H2O and en. Crystal data 1, orthorhombic, Cmcm space group, a=11.624(2), b=9.968(2), c=14.900(3) Å, R1=0.0298, wR2=0.1172. Compound 1 possesses a three-dimensional open-framework with β-cage and is an antiferromagnetic matter.
Keywords :
Three-dimensional , Cobalt oxalate-vanadate , Hydrothermal synthesis , Hybrid material , Cage
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
