Title of article :
Zinc complex of N-confused calix[4]phyrin
Author/Authors :
Hiroyuki Furuta، نويسنده , , Tomoya Ishizuka، نويسنده , , Atsuhiro Osuka، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Å longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.
Keywords :
Isoporphyrin , Zinc complex , Side-on ?1-coordination , Organometallics , N-confused porphyrin
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
