Title of article :
Modulation of photoinduced energy-transfer between Ru(II) and Os(II) termini in a dinuclear complex by a conformational change induced by Ba2+ binding at a central macrocyclic site
Author/Authors :
Rowena L Paul، نويسنده , , Angeles Farr?n Morales، نويسنده , , Gianluca Accorsi، نويسنده , , Thomas A Miller، نويسنده , , Michael D Ward، نويسنده , , Francesco Barigelletti، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
In a dinuclear complex containing {Ru(bpy)3}2+ and {Os(bpy)3}2+ termini separated by a flexible diaza-18-crown-6 macrocyclic spacer, binding of a Ba2+ ion at the central macrocycle results in an increase in the Ru⋯Os separation for electrostatic reasons, and hence a decrease in the efficiency of Ru→Os photoinduced energy-transfer.
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
