Title of article
Palladium mediated activation of a C–F bond in pentafluoropyridine: synthesis, structure and reactivity of a pyridyloxy complex
Author/Authors
Thomas Braun، نويسنده , , Sascha Rothfeld، نويسنده , , Verena Schorlemer، نويسنده , , Anja Stammler، نويسنده , , Hans-Georg Stammler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
752
To page
755
Abstract
[PdMe2(tmeda)] (1) reacts with pentafluoropyridine in the presence of water and triethylamine to give the aryloxy compound [PdMe(OC5NF4)(tmeda)] (2). The structure of 2 has been determined by X-ray crystallography. The palladium oxygen distance to the aryloxy ligand is 2.0368(14) Å. Treatment of 2 with Me3SiCl effects the cleavage of the palladium oxygen bond and the silane 4-C5NF4(OSiMe3) (3) is formed.
Keywords
Extensive hydrogenbond , crystal structure , Copper(II) complex
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1316076
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