Title of article
Two novel Zn(II) helical chain polymers containing both bridging and terminal carboxylato groups
Author/Authors
Chirantan Roy Choudhury، نويسنده , , Amitabha Datta، نويسنده , , Volker Gramlich، نويسنده , , G.M. Golzar Hossain، نويسنده , , K.M. Abdul Malik، نويسنده , , Samiran Mitra، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
790
To page
793
Abstract
Two novel carboxylato-bridged Zn(II) polymeric complexes [Zn(L)(CCl3COO)]n and [Zn(L)(CF3COO)]n, where [L=2-N-(2′-pyridylimine)benzoic acid] have been synthesized and structurally characterized. The structures of the two complexes are similar with the Zn(L)(Cl3CCO2) or Zn(L)(F3CCO2) units being repeated to form infinite helical chains. In each structure, the neighbouring Zn atoms are bridged sequentially by syn–anti carboxylate groups of the Schiff base.
Keywords
zinc , Carboxylate , Helical chain , crystal structure , Schiff base
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1316086
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