Title of article
Conversion of Al13 Keggin ε into Al30: a reaction controlled by aluminum monomers
Author/Authors
Lionel Allouche، نويسنده , , Francis Taulelle، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
1167
To page
1170
Abstract
In situ 27Al NMR experiments under hydrothermal and room temperature conditions demonstrate that aluminum monomers are the species controlling the Al13 Keggin ε conversion into Al30. New 27Al NMR signatures of Keggin-type aluminum polycation are observed in solution. A chemical pathway is proposed to explain the isomerization process.
Keywords
27Al NMR , Isomerization , Al13 , Al30 , Aluminum polycations
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1316175
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