Title of article
The first hetero-binuclear alkoxide of iron and vanadium: structural and spectroscopic features
Author/Authors
Giovana G. Nunes، نويسنده , , Geraldo R. Friedermann، نويسنده , , Marcelo H. Herbst، نويسنده , , Ricardo B. Barthem، نويسنده , , Ney V. Vugman، نويسنده , , J.Elaine Barclay، نويسنده , , David J. Evans، نويسنده , , Peter B. Hitchcock، نويسنده , , G.Jeffery Leigh، نويسنده , , Eduardo L. S?، نويسنده , , Ja??sa F. Soares، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
1278
To page
1281
Abstract
The immediate reaction between [V2(μ-OPri)2(OPri)6] (A) and [Fe2(μ-I)2I2(HOPri)4] (B) in toluene/propan-2-ol gives the novel mixed-metal [FeI2(μ-OPri)2V(OPri)2(HOPri)] (C). Structural, spectroscopic and magnetochemical characterisation are all consistent with a non-oxo vanadium(IV)/high-spin iron(II) formulation; variable-temperature X-band EPR spectra reveal an S=1/2↔S=1 equilibrium involving the vanadium centres in propan-2-ol solution.
Keywords
Heterometallic , Iron(II) , Binuclear , Alkoxide , Non-oxo vanadium(IV)
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1316203
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