Title of article :
Synthesis and characterization of silver(I) complexes [AgL]2[BF4]2 and [Ag(OAc)L]∞ [L=(CH2NHCOC2H4PPh2)2]
Author/Authors :
Yat Li، نويسنده , , Ka-Fu Yung، نويسنده , , Hoi-Shan Chan، نويسنده , , Wing-Tak Wong، نويسنده , , Wai Kwok Wong، نويسنده , , Man-Chung Tse، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The interaction of (CH2NHCOC2H4PPh2)2, L, with one equivalent of AgBF4 and AgOAc gave [AgL]2[BF4]2 1 and [Ag(OAc)L]∞ 2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent 31P{1H} NMR spectra.
Keywords :
Silver(I) complex , Bis(ethylamidophosphine) , crystal structure , Temperature-dependent 31P{1H} NMR study
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
