Title of article
Nitrosyl ruthenium complex as nitric oxide delivery agent: synthesis, characterization and photochemical properties
Author/Authors
Fabiana de Souza Oliveira، نويسنده , , Vanessa Togniolo، نويسنده , , Thais T Pupo، نويسنده , , Antonio Claudio Tedesco، نويسنده , , Roberto Santana da Silva، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
5
From page
160
To page
164
Abstract
In the present study, we report the synthesis, physical chemistry and photochemical properties of trans-[RuCl([15]aneN4)NO]2+ in physiological solution. The nitrosyl ruthenium species undergoes one-electron reduction in aqueous solution producing trans-[RuCl([15]aneN4)H2O]+ and nitric oxide (NO). The NO was also obtained with a laser flash-photolysis at 355 nm of trans-[RuCl([15]aneN4)NO]2+ in aqueous solution. The quantum yield for NO release was determined as 0.61 ± 0.05 mol einstein−1.
Keywords
Ruthenium macrocyclic complex , nitric oxide , Nitrosyl complexes
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316297
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