Title of article :
The preparation and complexation of 5,10-bis(diphenylphosphino)phenazine
Author/Authors :
Mireia Rodriguez i Zubiri، نويسنده , , Heather L. Milton، نويسنده , , David J. Cole-Hamilton، نويسنده , , Alexandra M.Z Slawin، نويسنده , , J. Derek Woollins، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Abstract :
Reaction of 5,10-dihydrophenazine with two equivalents of Ph2PCl, in the presence of n-BuLi at −78 °C in thf gives Ph2PN(C6H4)(C6H4)NPPh2 (1) which can be oxidised with selenium to Ph2P(Se)N(C6H4)(C6 H4)NP(Se)Ph2 (2) or coordinated with Pt(II) in cis-[PtCl2{Ph2PN(C6H4)(C6H4)NPPh2}] (3) The structure of 3 reveals a severely distorted (non-planar) phenazine backbone.
Keywords :
X-ray crystallography , Synthesis , structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
