Title of article
Discernible apical coordination in μ3-oxo-bridged mixed metal trinuclear carboxylate [Fe2MnO(CHCl2COO)6(THF)2H2O]
Author/Authors
Sergiu Shova، نويسنده , , Denis Prodius، نويسنده , , Valeriu Mereacre، نويسنده , , Yurii A. Simonov، نويسنده , , Janusz Lipkowski، نويسنده , , Constantin Turta، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
292
To page
295
Abstract
Novel μ3-oxo-bridged heterotrinuclear iron(III)-manganese(II) carboxylate of the composition [Fe2MnO(CHCl2COO)6(THF)2H2O] has been synthesized and characterized by X-ray crystallography, IR and TG. The positional parameters of the various metal ions within trinuclear [Fe2MnO]6+ core were determined unambiguously due to their different coordination environment and hydrogen bonds forming between two H2O molecules coordinated to Mn ions in different clusters.
Keywords
Hydrogen bonding , Iron(III) manganese(II) heterocluster , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316334
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