Title of article
Action of triphenylphosphine on [Rh(HCOO)(PPh3)2(CO)]. A novel synthetic route to [HRh(PPh3)3(CO)]
Author/Authors
Yuri S Varshavsky، نويسنده , , Tatiana G Cherkasova، نويسنده , , Ivan S Podkorytov، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
3
From page
489
To page
491
Abstract
Rhodium(I) carbonyl formato complex, trans-[Rh(HCOO)(PPh3)2(CO)], on heating in propanol-2 in the presence of excess triphenylphosphine converts into carbonyl hydride complex, [HRh(PPh3)3(CO)], with a good yield. The reaction provides a new and attractive method of synthesis of [HRh(PPh3)3(CO)].
Keywords
Rhodium , Format , Carbonyl hydride
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316389
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