Title of article :
The first specimen of tetranuclear (FeIII, LnIII) clusters assembled by carboxylate ligands: synthesis, structure, Mössbauer spectra, and magnetic properties of [Fe3EuO2(CCl3COO)8H2O(THF)3] · THF
Author/Authors :
Constantin Turta، نويسنده , , Denis Prodius، نويسنده , , Valeriu Mereacre، نويسنده , , Sergiu Shova، نويسنده , , Maria Gdaniec، نويسنده , , Yurii A. Simonov، نويسنده , , Victor Kuncser، نويسنده , , Mircea Bulinski and George Filoti، نويسنده , , Andrea Caneschi، نويسنده , , Lorenzo Sorace، نويسنده ,
Abstract :
The reaction of the neutral cluster [Fe2BaO(CCl3COO)6(THF)6] with Eu(NO3)3 · 6H2O in methanol affords novel tetranuclear Fe–Eu complex [Fe3EuO2(CCl3COO)8H2O(THF)3] · THF (1), which displays interesting Mössbauer spectra and magnetic behaviour.
