Title of article
Re(I)(tricarbonyl)+ complexes with anionic N∩S− thioxalato ligand
Author/Authors
Rafal Czerwieniec، نويسنده , , Andrzej Kapturkiewicz، نويسنده , , Jacek Nowacki، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
34
To page
37
Abstract
Reaction of Re(CO)5Cl with 8-thiohydroxyquinoline hydrochloride (HSX × HCl) afforded the dimeric Re2(CO)6(SX)2 complex with the structure supported by X-ray crystallography. Re2(CO)6(SX)2 reacts with boiling pyridine giving monomeric product Re(CO)3(SX)(pyr). The UV–Vis absorption and emission properties of the new image complexes have been discussed and compared with the properties of analogical species with the N∩O− ligands.
Keywords
8-thiohydroxyquinoline , Rhenium , Transition metal complexes , UV–Vis spectroscopy , X-ray crystallography
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316617
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