Title of article :
X-ray crystal structure, EPR and electrochemical studies of two novel cyanonitrosylrhenates: K2[Re(NO)(CN)5] · (Phen)6 · 4.5H2O and K[Re(NO)(H2O)(CN)4] · (Phen)5 · CH3OH · 3H2O
Author/Authors :
Sujoy RoyChowdhury، نويسنده , , Subhajit Dinda، نويسنده , , Santu Chakraborty، نويسنده , , Corine Simonnet، نويسنده , , Alok K. Mukherjee، نويسنده , , Ken-ichi Okamoto، نويسنده , , Ramgopal Bhattacharyya، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The reaction of an aqueous solution containing KReO4, KCN, KOH and NH2OH · HCl with Phen (1,10-phenanthroline) produced a light orange product which on crystallization from water or methanol afforded K2[Re(NO)(CN)5] · (Phen)6 · 4.5H2O (1) and K[Re(NO)(H2O)(CN)4] · (Phen)5 · CH3OH · 3H2O (2). In both complexes the metal oxidation state was confirmed by the EPR spectroscopy and the redox behavior was studied by cyclic voltammetry and differential pulse voltammetry.
Keywords :
Metal nitrosyl complex , Cyanonitrosylrhenates , crystal structure , 1 , 10-Phenanthroline
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
