Title of article
Reaction of [Pt3(μ-CO)3(PCy3)3] with tin dichloride
Author/Authors
Zolt?n Béni، نويسنده , , Rosario Scopelliti، نويسنده , , Raymond Roulet، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
3
From page
99
To page
101
Abstract
The reaction of [Pt3(μ-CO)3(PCy3)3] with SnCl2 · 2H2O forms [Pt3(μ-CO)2(μ-SnCl2)2(PCy3)3] which has two SnCl2 units bridging the same Pt–Pt edge in a butterfly geometry as shown by X-ray analysis. At low temperature, this cluster has the same structure in solution as in the solid state but is thermally unstable at room temperature.
Keywords
Platinum–tin clusters , Coordination compounds , crystal structure , NMR
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316635
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