Title of article
Magnesium dicarboxylates: First structurally characterized oxydiacetate and thiodiacetate magnesium complexes
Author/Authors
Abdessamad Grirrane، نويسنده , , Antonio Pastor، نويسنده , , Eleuterio Alvarez، نويسنده , , Agust?n Galindo، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
453
To page
456
Abstract
Novel magnesium oxydiacetate and thiodiacetate complexes, [{Mg(oda)(H2O)2} · H2O]n (1) image and [Mg(tda)(H2O)3] · H2O (2) image, were synthesized from the reaction of aqueous solutions of magnesium dichloride with a 1:1 mixture of Na2CO3 and oxydiacetic acid or thiodiacetic acid, respectively. Complex 1 is a one-dimensional polymer with a planar bridging oxydiacetate ligand in a meridional disposition, whereas 2 is a monomer containing the typical tridentate thiodiacetate ligand with a facial configuration.
Keywords
crystal structure , Magnesium , Oxydiacetate , Thiodiacetate , Diglycolate , Thiodiglycolate
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316724
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