Title of article
A self-assembled molecular ladder with Cu(H2O)4 units as cross rungs
Author/Authors
Ben-Yong Lou، نويسنده , , Da-Qiang Yuan، نويسنده , , Ben-Lai Wu، نويسنده , , Lei Han، نويسنده , , Fei-Long Jiang، نويسنده , , Mao-Chun Hong، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
539
To page
542
Abstract
The self-assembly of salicylaldehyde, d,l-aspartic acid and Cu(NO3)2 · 3H2O gave a 1D molecular ladder {[Cu2(sasp)2Cu(H2O)4] · 0.5H2O}n (1) in which Cu(H2O)4 units serve as cross rungs and two sasp–Cu–sasp–Cu chains with opposite chirality serve as side rails. Compound 1 displays strong antiferromagnetic interactions within Cu3O2 trinuclear units and weak interunit ferromagnetic interactions. Interchain hydrogen bonds result in weak antiferromagnetic interactions.
Keywords
N-Salicylideneaspartic acid , Ferromagnetic , Molecular ladder , Hydrogen bonding , Cu(II) , Antiferromagnetic
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316746
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