Title of article
Selective formation of lanthanide(III) complexes with polyaminopolycarboxylate: Unprecedented tetranuclear neodymium(III) complex containing alkoxo and carboxylato bridges
Author/Authors
Yoshitaro Miyashita، نويسنده , , Masateru Sanada، نويسنده , , Md. Monirul Islam، نويسنده , , Nagina Amir، نويسنده , , Tamotsu Koyano، نويسنده , , Hiroshi Ikeda، نويسنده , , Kiyoshi Fujisawa، نويسنده , , Ken-ichi Okamoto، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
785
To page
788
Abstract
Crystal structures of the novel polynuclear Nd(III) complexes, Na4[{Nd(H2O)}2(μ2-dptaO)2] (1) and K8[Nd2{Nd(H2O)2}2(μ2-dptaO)2(μ3-dptaO)2] (2) (H4dptaOH = 2-hydroxypropane-1,3-diamine-N,N,N′,N′-tetraacetic acid), which were selectively formed depending on the difference of counter cations, were determined. These complexes showed weak antiferromagnetic behavior.
Keywords
X-ray crystal structure , Alkoxo-bridged complex , Carboxylato-bridged complex , Nd(III) complex , Polyaminopolycarboxylate
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316807
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