Title of article :
Titanium complexes supported by a sterically encumbering N-anchored tris-arylphenoxide ligand
Author/Authors :
Sara A. Cortes، نويسنده , , Miguel A. Mu?oz Hern?ndez، نويسنده , , Hidetaka Nakai، نويسنده , , Ingrid Castro-Rodriguez، نويسنده , , Karsten Meyer، نويسنده , , Alison R. Fout، نويسنده , , Deanna L. Miller، نويسنده , , John C. Huffman، نويسنده , , Daniel J. Mindiola، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
A family of neutral and cationic Ti(IV) complexes supported by the sterically demanding and trianionic ligand (O3N)3− (O3N3− = tris(2-O,3-Ad,5-tBubenzyl)amine, Ad = 1-adamantyl) have been prepared from the hydrolysis of TiCl4(THF)2 with the free base (O3N)H3 and excess NEt3, followed by anion exchange reactions. These (O3N)Ti+ cores are resistant to moisture and air, are mononuclear, and possess C3 symmetry on the NMR timescale.
Keywords :
Tripodal ligands , N-anchored , titanium complexes , Trianionic-amines , X-ray structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
