Title of article :
Synthesis and crystal structure of metal (M = Ag, Cu) crown ether with N-heterocyclic carbene linkage
Author/Authors :
Xiangjian Wan، نويسنده , , Feng-Bo Xu، نويسنده , , Qingshan Li، نويسنده , , Hai-Bin Song، نويسنده , , Zheng-Zhi Zhang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Reaction of the carbene precursor 1 and Ag2O yields the Ag(I) metal crown ether 2a. Carbene transmetalation reaction of 2a with CuI gives Cu(I) analogue 2b. The structures of 2a and 2b are determined by X-ray crystallography.
Keywords :
N-heterocyclic carbene , Metallacrown ether , crystal structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
