Title of article :
Synthesis and structure of image: A new member of anion encapsulating metallamacrocyles
Author/Authors :
Tereza Afrati، نويسنده , , Catherine Dendrinou-Samara، نويسنده , , Curtis M. Zaleski، نويسنده , , Jeff W. Kampf، نويسنده , , Vincent L. Pecoraro، نويسنده , , Dimitris P. Kessissoglou، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The reaction of copper(II) perchlorate with di-2-pyridyl ketone oxime yields the first 18-MC-6 complex with M–N–O connectivity, [Cu6(pko)6ClO4(CH3CN)6] [Cu6(pko)6(ClO4)3(CH3CN)4] · 8ClO4 · 14CH3CN · H2O 1. In the solid state the cationic complex encapsulates a perchlorate anion within the central cavity. Magnetic susceptibility measurements reveal that the complex is diamagnetic. EPR measurements indicate that the complex dissociates in DMF.
Keywords :
Metallamacrocycle , Copper complex , crystal structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
