Title of article
Metal ion promoted hydrolysis of nitrile-functionalized triazamacrocycle
Author/Authors
Zhong Zhang، نويسنده , , Ying He، نويسنده , , Qun Zhao، نويسنده , , Wei Xu، نويسنده , , Yi-Zhi Li، نويسنده , , Zhi-Lin Wang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
269
To page
272
Abstract
The triazamacrocyclic ligand L functionalized with nitrile pendant arms undergoes metal-promoted hydrolysis in undried CH3CN to afford amide derivative L1 followed by the formation of a complex [ZnL1](ClO4)2 (1), which was structurally characterized. Furthermore, unexpected metal-assisted decyanomethylation reaction of the ligand L was observed via electrospray ionization mass spectrum (ESI-MS) when aqueous CH3CN was employed as the reaction solvent.
Keywords
Hydrolysis , Azamacrocycle , Nitrile pendant arm , ZnII complexes , Decyanomethylation
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1316971
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