Title of article
[Cu5Cl(4,4′-bipy)5][SiW12O40] · 1.5H2O: A novel three-dimensional framework constructed from polyoxometalate clusters and trinuclear Cu(I) complex
Author/Authors
Hua Jin، نويسنده , , Chao Qin، نويسنده , , Yangguang Li، نويسنده , , En-Bo Wang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
482
To page
485
Abstract
An unprecedented organic–inorganic hybrid compound [Cu5Cl(4,4′-bipy)5] [SiW12O40] · 1.5H2O (1) has been hydrothermally synthesized and characterized by elemental analyses, IR, TG analyses, cyclic voltammetry and single-crystal X-ray diffraction. To our best knowledge, it is the first time that saturated Keggin-type polyoxoanions are covalently linked by trinuclear Cu(I) complex into a three-dimensional structure.
Keywords
Chlorine atom , Keggin-type polyoxometalate , Hydrothermal synthesis , Trinuclear copper cluster
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317026
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