Title of article
Synthesis and characterization of the first polyoxometalate possessing bicapped by antimony α-Keggin structure
Author/Authors
Qing-Bin Zhang، نويسنده , , Yu-Kun Lu، نويسنده , , Ya-Bing Liu، نويسنده , , Jing Lu، نويسنده , , Ming-Hui Bi، نويسنده , , Jie-Hui Yu، نويسنده , , Tie-Gang Wang، نويسنده , , Ji-Qing Xu*، نويسنده , , Jian Liu، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
544
To page
547
Abstract
A novel polyoxometalate image (1) has been synthesized in the system of Sb2O3-(NH4)6Mo7O24 · 4H2O-H3PO4-en-H2O under hydrothermal conditions and characterized by IR, TGA, elemental analyses, single crystal X-ray diffraction and XPS. Interestingly, compound 1 displays three-dimensional network consisting of one-dimensional sinusoidal chain [(Hen)2(H2O)2]2+ and two-dimensional layer formed by image. The structure unit image is the first example of bicapped by antimony α-Keggin structure.
Keywords
Bicapped ?-Keggin , Antimony , Polyoxometalate , Hydrothermal synthesis
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317043
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