Title of article
The first example of Re(IV)-mediated nitrile–hydroxylamine coupling
Author/Authors
Konstantin V. Luzyanin، نويسنده , , Vadim Yu. Kukushkin، نويسنده , , Matti Haukka، نويسنده , , Armando J.L. Pombeiro، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
732
To page
735
Abstract
The metal-mediated coupling between the acetonitriles in cis-[ReIVCl4(MeCN)2] and the N,N-dibenzylhydroxylamines image (R3 = CH2Ph, CH2C6H4C1-p) proceeds smoothly in CH2Cl2/MeCN at 20–25 °C for ca. 15 min to accomplish new imino species image (R3 = CH2Ph, 1, CH2C6H4C1-p, 2) in ca. 70% yield. The structures of the isolated compounds were based on elemental analyses (C, H, N), IR, FAB+-MS and on X-ray data for 1.
Keywords
nitriles , Metal-mediated reactions , Imino complexes , Rhenium(IV) complexes , Nucleophilic addition , Dibenzylhydroxylamines
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317088
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