Title of article
Cyano-bridged one-dimensional chain containing mixed-valent Ru2(II,III) dinuclear unit
Author/Authors
Wei Liu، نويسنده , , Emmanuel Ngwang Nfor، نويسنده , , Yi-Zhi Li، نويسنده , , Jing-Lin Zuo، نويسنده , , Xiao-Zeng You، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
3
From page
923
To page
925
Abstract
Using tricyanometalate [(Tp)Fe(CN)3]− (Tp− = hydrotris(pyrazolyl)borate) as building block, the 1-D chain polymer containing paramagnetic Ru2(II,III) dinuclear complex, [Ru2(O2CtBu)4][(Tp)Fe(CN)3] (1), was synthesized and its structure was determined. Magnetic measurements indicate that there is antiferromagnetic interaction between Ru2 units (s = 3/2) and low-spin FeIII ions (s = 1/2).
Keywords
Diruthenium , Chain complexes , Magnetic properties , crystal structures , Cyanide
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317137
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