Title of article
Synthesis and characterization of first hetero-nuclear molybdenum copper cluster with highly delocalized Cu(I)/Cu(II)
Author/Authors
Ying-Hua Sun، نويسنده , , Jie-Hui Yu، نويسنده , , Xiang-Jun Jin، نويسنده , , Jiang-Feng Song، نويسنده , , Ji-Qing Xu*، نويسنده , , Ling Ye، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
1087
To page
1090
Abstract
A novel molybdenum–copper cluster with highly delocalized mixed-valence Cu(I)/Cu(II) [MoO3Cu2(obipy)2]2O (1), has been hydrothermally synthesized and characterized by the elemental analyses, IR, XPS, TG analysis and the single crystal X-ray diffraction. The feature of 1 is that two copper atoms have different coordination configuration and valences. Variable temperature magnetic susceptibility measurements show the occurrence of a weak ferromagnetic interaction in 1.
Keywords
Hydrothermal synthesis , Hydroxylation , Hetero-nuclear cluster , Mixed-valence copper
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317179
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