Title of article
A trinuclear anionic trifluoroacetato derivative of iron(II) containing a central O(–I) ligand
Author/Authors
Alberto Albinati، نويسنده , , Fausto Calderazzo، نويسنده , , Fabio Marchetti، نويسنده , , Sax A. Mason، نويسنده , , Bernardo Melai، نويسنده , , Guido Pampaloni، نويسنده , , Silvia Rizzato، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
4
From page
902
To page
905
Abstract
The reaction of Fe(CO)5 with CF3COOH/(CF3CO)2O, or with CF3COOH, in DMF at about 140 °C produces the colourless compound 1, [Fe(DMF)6][Fe3(μ3-O) (CF3COO)6(DMF)3]2, constituted by the [Fe(DMF)6]2+ cation and by two [Fe3(μ3-O)(μ2-CF3COO)6(DMF)3]− anions, with a triangular disposition of the three iron atoms, the central substantially coplanar oxygen atom being formulated as a singly charged anion O(–I) stabilized by complexation to iron(II).
Keywords
Neutron-diffraction , Iron(II) , M3O system , Single crystal
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317450
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