Title of article :
Two-way synthesis of a double-lantern heterobimetallic complex [Pd(μ-OOCMe)4Co]2(μ-OOCMe)2Pd(py)2
Author/Authors :
Sergei E. Nefedov، نويسنده , , Ilya A. Yakushev، نويسنده , , Natalia Yu. Kozitsyna، نويسنده , , Zhanna V. Dobrokhotova، نويسنده , , Vladimir N. Ikorsky، نويسنده , , Michael N. Vargaftik، نويسنده , , Ilya I. Moiseev، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
The lantern complex PdII(μ-OOCMe)4CoII(NCMe) (1) was transformed into the pentanuclear double-lantern acetate-bridged heterobimetallic complex [Pd(μ-OOCMe)4Co]2(μ-OOCMe)2Pd(py)2 (py is pyridine) (2) by two routes: (i) reaction of 1 with pyridine and (ii) reaction of 1 with trans-Pd(py)2(OOCMe)2. Complex 2 × 3C6H6 was characterised by single-crystal X-ray diffraction, DTA-TG and magnetic susceptibility data.
Keywords :
X-ray structure , Pyridine , Magnetic susceptibility , Thermogravimetry , Heterobimetallic acetate complexes , Palladium , Cobalt
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
