Title of article :
An alternating chain consisting of dinuclear Cu(II) ions bridged by end-on bis(μ-dicyanamido-κN1,N5) ligands and hydrogen-bonded pairs of bis(pyrimidin-2-yl)amines, with unusually long Cu⋯Cu distances of 7.20 and 9.99 Å: Synthesis, structure and magnetic
Author/Authors :
Gerard A. van Albada، نويسنده , , Maarten G. van der Horst، نويسنده , , Ilpo Mutikainen، نويسنده , , Urho Turpeinen، نويسنده , , Jan Reedijk، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
A novel bis (end-to-end) bridged dicyanamide dinuclear copper(II) compound with the general formula [Cu(dipm)(μ-dca)(H2O)(ClO4)]2 · 2EtOH (in which dipm = bis(pyrimidin-2-yl)amine) has been synthesised and characterised by X-ray crystallography and infrared spectroscopy. In addition, EPR and magnetic measurements have been performed.
Keywords :
Hydrogen bond , Dicyanamide , crystal structure , Dinuclear , copper
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
