Title of article
New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand: Synthesis, crystal structure and magnetic properties
Author/Authors
Jianwei Lu، نويسنده , , Yao-Hsuan Huang، نويسنده , , Shun-Jin Lo، نويسنده , , Ho-Hsiang Wei، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
4
From page
1210
To page
1213
Abstract
A new μ-oxo-bridged Cu(II) complex with cubane-like tetranuclear copper(II) complex, [Cu4(L1)4] · 4H2O (1) (H2L1 = 2-(3-methoxy-salicylidene-amino)-benzyl-alcohol), has been prepared, and structurally characterized by X-ray crystallography. Complex 1 crystallized in the monoclinic space group P21/n and has a tetranuclear core of Cu4O4. The temperature dependence of magnetic susceptibility measurements shown that complex 1 exhibits a strong antiferromagnetic interaction with J = −103.4 cm−1.
Keywords
Magnetic properties , crystal structure , Copper(II) clusters , Copper(II) complexes
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317526
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