Title of article
A novel dianionic seven-coordinate complex of tungsten(II), [WCl3(GeCl3)(CO)3]2−: Synthesis, spectroscopic properties and X-ray crystal structure
Author/Authors
Anna Malinowska، نويسنده , , Marcin G?rski، نويسنده , , Andrzej Kochel، نويسنده , , Teresa Szyma?ska-Buzar، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
3
From page
1233
To page
1235
Abstract
A new dianionic complex of tungsten(II), [(WCl3(GeCl3)(CO)3]2− (12−), containing the piperidinium cations [Hpip]+ as the counter ions, has been obtained from the reaction between [W(CO)4(pip)2] and GeCl4 in dichloromethane solution, and its molecular structure has been elucidated by single-crystal X-ray diffraction studies. The chemical properties of complex 1 were investigated by IR and NMR spectroscopy in solution.
Keywords
Germyl ligand , Heterobimetallic complex , Seven-coordinate complex , X-ray crystal structure , Tungsten(II)
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317532
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