Title of article
A photoluminescent hexanuclear silver(I) complex exhibiting C–H⋯Ag close interactions
Author/Authors
Chun-Sen Liu، نويسنده , , Pei-Quan Chen، نويسنده , , Ze Chang، نويسنده , , Jun-Jie Wang، نويسنده , , Li-Fen Yan، نويسنده , , Hongwei Sun، نويسنده , , Xian-He Bu، نويسنده , , Zhenyang Lin، نويسنده , , Zheng-Ming Li، نويسنده , , Stuart R. Batten، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
5
From page
159
To page
163
Abstract
The reaction of AgNO3 with bulky anthracene-9-carboxylic acid (HL1) in the presence of 2,6-dimethylpyridine (dmp) afforded a photoluminescent hexanuclear discrete AgI complex [Ag6(L1)6(dmp)2] exhibiting C–H⋯Ag interactions whose total interaction energy were further estimated by DFT calculations. The relevant results reveal that the steric bulk of the anthracene ring skeleton of L1 may play important roles in the formation of the final structure.
Keywords
crystal structures , Luminescence , DFT calculations , C–H?Ag close interactions , Photoluminescent Silver(I) complexes , Bulky aromatic skeletons
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317653
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