Title of article :
{[Cu2(μ-Cl)(μ-dppm)2](μ2-TCNQ)}∞, a charge transfer compound derived from a donor with a copper dimer
Author/Authors :
Yong-qin Song، نويسنده , , Qi-ying Lv، نويسنده , , Shuzhong Zhan، نويسنده , , Jian-ge Wang، نويسنده , , Jia-yin Su، نويسنده , , An Ding، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
The reaction of CuCl, dppm (bis(diphenylphosphino)methane), and TCNQ with a molar ratio set of 2:2:1 produced a one-dimensional compound 1 {[Cu2(μ-Cl)(μ-dppm)2](μ2-TCNQ)}∞. Its structure was determined by X-ray crystallography. The new compound 1 was studied by IR and UV/Vis/NIR spectroscopy. 1 exhibits an intervalence transfer transition at λ = 1296 nm, and also appears photoluminescence (λmax = 818 nm) at room temperature.
Keywords :
N ligands , Luminesence , Charge transfer , Copper dimer
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
