Title of article
Novel lanthanide–iminodiacetate frameworks with hexagonal pores
Author/Authors
Carlos Kremer، نويسنده , , Paula Morales، نويسنده , , Julia Torres، نويسنده , , Jorge Castiglioni، نويسنده , , Javier Gonzalez-Platas، نويسنده , , Markus Hummert، نويسنده , , Herbert Schumann، نويسنده , , Sixto Dom?nguez، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
862
To page
864
Abstract
A new family of lanthanide complexes with open-framework structures has been prepared and characterized by X-ray diffraction. The structure of the polymers with general formula [Ln(Hida)3] · xH2O (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb; H2ida = iminodiacetic acid) presents large hexagonal channels with more than 11 Ǻ diameter, and houses the crystallization water molecules. These molecules can be reversibly removed upon heating. This is the first example of this kind of structure with ida as bridging ligand.
Keywords
crystal structure , Lanthanide , Coordination polymer , Iminodiacetate
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317826
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