Title of article :
A polyoxoanion with an unusual [Sb6O16(OH)12] cluster skeleton and S4 molecular symmetry [Mo4Sb6(OH)12O24]6−
Author/Authors :
Yanzhong Zhen، نويسنده , , Qiang Shen، نويسنده , , Lili Li، نويسنده , , Ganglin Xue، نويسنده , , Huaimin Hu، نويسنده , , Feng Fu، نويسنده , , Jiwu Wang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
A rich antimony polyoxoanion [Mo4Sb6(OH)12O24]6− was crystallized as potassium salt in neutral aqueous solution and characterized by IR, UV–vis spectra, CVs and single crystal X-ray diffraction. X-ray structural analysis shows that the polyanion [Mo4Sb6(OH)12O24]6− has S4 molecular symmetry and a ellipsoid-shape structure built of an unusual [Sb6O16(OH)12] framework capped with four segregated {MoO2} groups.
Keywords :
crystal structure , Molybdenum , Antimony , Polyoxanion
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
