Title of article
A new self-assembled μ6-sulfato hexanuclear cobalt(II) complex of a symmetric dinucleating ligand: Synthesis and X-ray structural analysis
Author/Authors
Manindranath Bera، نويسنده , , Ashley B.S. Curtiss، نويسنده , , Ghezai T. Musie، نويسنده , , Douglas R. Powell، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
4
From page
1033
To page
1036
Abstract
A novel μ6-sulfato hexanuclear cobalt(II) complex, Na2[Co6(Hccdp)3(μ6-SO4)] · 30H2O (1) was isolated from the reaction of CoSO4 · 7H2O with ligand H5ccdp (where H5ccdp = N,N′-Bis[2-carboxybenzomethyl]-N,N′-Bis[carboxymethyl]-1,3-diaminopropan-2-ol) in the presence of NaOH in aqueous-acetonitrile solution and its X-ray crystal structure has been determined. The structure of 1 contains a image core unit which is held together by three heptadentate bridging ligands, Hccdp4−.
Keywords
Dinucleating bridging ligand , Hexanuclear , Cobalt(II) complex , Self-assembly , X-ray crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317875
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