Title of article
New homoleptic carbene transfer ligands and related coinage metal complexes
Author/Authors
Grazia Papini، نويسنده , , Giuliano Bandoli، نويسنده , , Alessandro Dolmella، نويسنده , , Giancarlo Gioia Lobbia، نويسنده , , Maura Pellei، نويسنده , , Carlo Santini، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
4
From page
1103
To page
1106
Abstract
The synthesis, spectroscopic and structural characterization of the carbene ligand precursor bis(4-benzyl-1,2,4-triazol-4-ium-1-yl)dihydroborate has been described. Treatment with Ag2O leads to the silver(I) complex of the new monoanionic bis(4-benzyl-1,2,4-triazol-5-ylidene-1-yl)dihydroborate dicarbene ligand. The resulting dimetallacycle carbene complex has been used to synthesize the homoleptic gold(I) complex by transmetallation reaction.
Keywords
2 , Silver(I) , Spectroscopy , 1 , Gold(I) , 4-Triazole , Scorpionates , X-ray , N-heterocyclic carbenes
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317896
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