Title of article
Factors that stabilize the image electron configuration in iron(III) porphyrinates: A case of bis(benzaldehyde) complex
Author/Authors
Akira Ikezaki، نويسنده , , Yoshiki Ohgo، نويسنده , , Taishi Watanabe، نويسنده , , Mikio Nakamura، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
4
From page
1198
To page
1201
Abstract
Analysis of the 1H and 13C NMR chemical shifts has revealed that bis-ligated iron(III) porphyrinates, [Fe(Porphyrin)(L)2]±, adopt the image ground state if the complex has highly ruffled porphyrin core and carries weak oxygen ligand with multiple bond such as benzaldehyde.
Keywords
Iron(III) , Porphyrin complexes , Intermediate-spin , Spin state , Electron configuration
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317922
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